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• W1005508105 abstract "A simple methodology for identifying possible higher order Mn+1AXn phases (n≥2) from the chemical characteristics of known phases was developed. The method was used to identify two potential M3AC2 phases Ti3GaC2 and Ti3InC2. After verifying that the n=1 MAX phases in these systems could be synthesised in bulk using a simple pressureless reactive sintering process, the new phases were synthesised using the same method. DFT calculations were used to test the thermodynamic stability of the new phases against the known competing phases within the same ternary systems. Both were found to be stable although Ti3InC2 only marginally so. Crystal structure refinements and comparison to other MAX phases revealed a linear increase in the c-axis length as a function of the atomic radius of the A element." @default.
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• W1005508105 date "2015-10-01" @default.
• W1005508105 modified "2023-10-16" @default.
• W1005508105 title "Ti3GaC2 and Ti3InC2: First bulk synthesis, DFT stability calculations and structural systematics" @default.
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• W1005508105 doi "https://doi.org/10.1016/j.jssc.2015.07.028" @default.
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