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- W1006157869 abstract "Publisher Summary This chapter focuses on circularly polarized luminescence. It investigates specifically how it is measured and what it may reveal about the molecules producing it. The occurrence of circularly polarized light in the luminescence of chiral molecules can be rationalized in terms of the known correspondence between absorption and emission processes. For a transition between two defined quantum levels, the probability of spontaneous emission is proportional to the probability of absorption at unit light intensity, and this is expected to hold separately for right-handed and left-handed circularly polarized light. In addition, there is another feature in circularly polarized luminescence (CPL) by which it differs from circular dichroism (CD), which should not be ignored particularly the orientational distribution of the molecules. In the case of CPL it is the orientational distribution of the population of excited molecules that is relevant, and it may be dramatically different from the orientational distribution of the population of the molecules in the ground state, which is relevant to CD measurements." @default.
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- W1006157869 date "1978-01-01" @default.
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- W1006157869 title "[7] Circularly polarized luminescence" @default.
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- W1006157869 doi "https://doi.org/10.1016/s0076-6879(78)49009-3" @default.
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