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• W1006157941 abstract "We report growth and investigation of structural and (photo−)electrical properties of CuInSe2– ZnIn2Se4 semiconductor crystals, grown by the horizontal Bridgman method. Their optical bandgap was evaluated from the absorption spectra. It increased monotonously from 1 eV up to 1.08 eV at 300 K with increasing amount of ZnIn2Se4 in the range of 5–20 mol%. All crystals had n-type electrical conductivity. The solid solutions containing 5–10 mol% ZnIn2Se4 had demonstrated weak temperature dependence of the electrical conductivity, high electron density and low photoconductivity. This evidences their nearly degenerate state. In the crystals with 15 and 20 mol% ZnIn2Se4 a variable range hopping conduction mechanism was found to dominate between ∼30 K and 110 K. Above 130 K it was changed by a thermally activated conductivity. The donor activation energy for the samples with 15 and 20 mol% ZnIn2Se4 were 0.018 eV and 0.04 eV, respectively. The characteristic feature of the spectral distribution of their photoconductivity at 30-70 K is presence of a narrow peak at 1160 – 1190 nm." @default.
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• W1006157941 date "2015-01-01" @default.
• W1006157941 modified "2023-09-27" @default.
• W1006157941 title "Growth and Analysis of Nanostructured CuInSe2-ZnIn2Se4 Solid Solutions: Their Electrical and Photoelectrical Properties" @default.
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• W1006157941 doi "https://doi.org/10.1016/j.matpr.2015.04.020" @default.
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