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- W1006822603 abstract "A novel manganiferous polymeric complex [(imid)2(ta)Mn0.5]n (imid = imidazole,ta = terephthalato) was synthesized by the hydrothermal reaction of MnO2, terephthalic acid,imidazole, and H2O. Structure analysis indicates that the compound crystallizes in the triclinic system, space group p1^-, with a = 8.1500(16), b = 8.5100(17), c = 9.0500(18) A, α = 72.77(3), β =65.50(3), γ = 77.22(3)°, V = 542.02(19) A^3, Z = 2, Dc = 1.505 g/cm^3, F(000) = 253, Mr = 245.69,μ(MoKα) = 0.655 mm^-1, R = 0.0733 and wR = 0.1703 for 1673 observed reflections (I > 2σ(Ⅰ)). The compound is characteristic of a zigzag chain-like framework built up of ta bridge and (Imid)4Mn group. The 1-D frameworks are held together by H-bonds between the dangling N-H donors from imid and O acceptors from ta." @default.
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- W1006822603 date "2005-01-01" @default.
- W1006822603 modified "2023-09-26" @default.
- W1006822603 title "Hydrothermal Synthesis and Structure of a Novel 1-D Mn（ll） Compound with Carboxlyto and Imidazole Ligands" @default.
- W1006822603 hasPublicationYear "2005" @default.
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