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- W1007772950 abstract "Publisher Summary Polyaryletherketones (PAEKs) are linear aromatic polymers exhibiting desirable physical properties and durability against environmental challenge. These properties are the direct result of the chemistry and architecture of the polymer backbone, the manner and extent to which the molecules organize when the polymer is solidified, and any morphological changes that occur during subsequent thermal exposure. It provides a discussion of the semicrystalline nature of the PAEKs and the techniques traditionally used to characterize their structures, including density, X-ray diffraction, Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), and microscopy. Importantly, the crystallization behavior of the PAEKs does not allow for the degree of crystallinity at room temperature to be obtained readily from DSC. This chapter also contains a description of the effects of thermal history, including annealing and quenching, on structure and physical properties. A brief review of the connection between composition, morphology, and basic physical properties such as stiffness, strength, elongation, and fatigue behavior of neat resins as well as PEEK composites is also given in the chapter. FTIR spectroscopy provides information related to the structure and mobility of dipoles and is commonly used to characterize polymeric materials. DSC provides a relative measure of heat flow that provides an insight into molecular motion. DSC is readily used to determine the heat capacity of a polymer, the glass transition temperature, and the melting point. Depending on the desired magnification, optical and electron microscopy may be useful to examine PAEK polymers. Both techniques can be used in reflection or transmission to provide insight into polymer structure." @default.
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- W1007772950 date "2012-01-01" @default.
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- W1007772950 title "Morphology and Crystalline Architecture of Polyaryletherketones" @default.
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