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- W1008621380 endingPage "86" @default.
- W1008621380 startingPage "21" @default.
- W1008621380 abstract "This chapter discusses the field of transition-metal complexes of isocyanides developed slowly over more than a century to a respectable subarea in coordination chemistry and which, in the process, seems to have attracted very little attention. The valence-bond pictures for an isocyanide and carbon monoxide and for metal complexes of these ligands emphasize the similarities of both the ligands and their complexes. The insertion of a carbonyl group into a metal–alkyl or metal–aryl bond and the reverse reaction involving decarbonylation of an acyl complex have been studied from both the synthetic and mechanistic points of view. The reactions of nucleophilic reagents with cationic and uncharged metal carbonyl complexes have received much attention in the past, and it is not surprising that these studies have now been extended to isocyanide metal complexes. Perhaps the greatest excitement in the field of metal isocyanide complex chemistry has been generated by the observation that a variety of protonic substances (alcohols, thiols, amines, and hydrazine) add to the coordinated isocyanide ligand. A number of chemists have been interested in the chemistry of cobinamine and cobaloxime complexes of several ligands, including isocyanides." @default.
- W1008621380 created "2016-06-24" @default.
- W1008621380 creator A5043010575 @default.
- W1008621380 date "1973-01-01" @default.
- W1008621380 modified "2023-10-11" @default.
- W1008621380 title "Transition Metal-lsocyanide Complexes" @default.
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