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- W100878150 abstract "The hydrodeoxygenation of methyl palmitate and methyl heptanoate as the model compounds of bio-oil in the presence of sulfided CoMo/γ-Al2O3 and NiMo/γ-Al2O3 catalysts was studied at the temperature 300°C and hydrogen pressure 35 bars. In hydrodeoxygenation experiments the performances of sulfided CoMo and NiMo catalysts were compared in terms of methyl palmitate and methyl heptanoate conversions, oxygen removal, and the reaction products distribution. The CoMo/γ-Al2O3 catalyst exhibited higher catalytic activity in the methyl palmitate HDO than the NiMo/γ-Al2O3 using n-tetradecane as a solvent. The main product obtained over CoMo/γ-Al2O3 catalyst was hexadecane whereas pentadecane is preferably formed over NiMo/γ-Al 2O3 catalyst, pointing to different reaction route of HDO. The tentative reaction scheme of methyl palmitate transformation was considered in comparison with ones obtained for methyl heptanoate hydrodeoxygenation." @default.
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- W100878150 date "2011-12-10" @default.
- W100878150 modified "2023-09-27" @default.
- W100878150 title "The comparison of sulfide CoMo/γ-Al 2 O 3 and NiMo/γ-Al 2 O 3 catalysts in methyl palmitate and methyl heptanoate hydrodeoxygenation" @default.
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