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- W1010349355 abstract "Australia has abundant reserves of natural gas, which are currently underutilized. These reserves are generally remote from the major population areas and are often offshore. The development of catalysts capable of dimerizing or oligomerizing olefins in the presence of H2, CO, and CO2, would remove the necessity of cryogenically separating these gases from ethylene, with consequent reductions in capital and production costs. Catalyst systems prepared from [Ni(dithio-β-diketonate)(PL1L2L3)X], [Ni(S2CNR2)], [Ni(S2CNR2)(PL1L2L3)X] or [Ni(S2COR)2] and alkylaluminium halides and hydrides are extremely effective in the isomerization, dimerization and oligomerization of low molecular weight olefins at around mom temperature. The catalyst activity can be reliably controlled by variations in the dithie and/or phosphine ligand substituents. The catalyst selectivity can be controlled by variations in the ligand substituents or choice of alkylaluminium co-catalyst. Catalysts highly selective for isomerization only, for dimerization or for oligomerization can be chosen. Similarly, the degree of branching of the products can also be controlled by catalyst selection. The catalysts operate with either neat or dilute olefin streams in the presence of low levels of H2, CO2, H2O and O2. Although some catalyst/co-catalyst combinations are inhibited by CO, the poisoning can often be reversed by removal of the CO. Other catalyst systems operate under a constant stream of CO at one atmosphere." @default.
- W1010349355 created "2016-06-24" @default.
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- W1010349355 date "1994-01-01" @default.
- W1010349355 modified "2023-09-26" @default.
- W1010349355 title "The Oligomerization of Dilute Ethylene Streams" @default.
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- W1010349355 doi "https://doi.org/10.1016/s0167-2991(08)63924-5" @default.
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