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- W1010515433 abstract "The elucidation of the chemical basis of the K vitamins is because of the schools of Dam, Doisy, and Karrer, who succeeded in 1939 in isolating two pure compounds with vitamin K activity, namely vitamin K1 (I) from alfalfa and vitamin K2 (II) from putrefied fish meal. The structure of vitamin K1 was proved by oxidative degradation and by synthesis to be 2-methyl-3-phytyl-1, 4-naphthoquinone, the side chain consisting of four isoprene units (4 ×5 = 20 C-atoms). It had been established that vitamin K2 contains the same ring system with a longer and more unsaturated side chain. This chapter summarizes the progress in chemistry and biochemistry of the naturally occurring K vitamins and their close analogs. In addition, the chapter reviews the observed differences in action between K vitamins and menadione and an attempt is made to explain them on biogenetic considerations." @default.
- W1010515433 created "2016-06-24" @default.
- W1010515433 creator A5009529917 @default.
- W1010515433 creator A5024124743 @default.
- W1010515433 date "1959-01-01" @default.
- W1010515433 modified "2023-10-18" @default.
- W1010515433 title "Chemistry and Biochemistry of the K Vitamins" @default.
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