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- W1018173698 abstract "Complex(Et4N)[ VFe3S4Cl3(CH3CN)3 ](1)has been obtained from(NH4)3VS4/FeCl2/NaHS/Et4NCl reaction system in CH3CN solvent and structurally characterized by X-ray diffraction analysis.It crystallizes in orthorhombic space group Pnma(No.62)with a=8.851(2),b=16.447(3),c=19.448(4)A,V=2865.6(10)A3,Z=4,Mr=706.49,Dc=1.638g/cm3,F(000)=1428,μ(MoKα)=2.385 cm- 1 and T=293(2)K.With use of 1467 observed reflections(I>2σ(Ⅰ))the structure was refined to R=0.0874 and wR=0.2065.Complex 1 contains a VFe3S4 cuboidal core with average V- Fe distance of 2.759(4)A,which is a little longer than Fe - Fe of 2.716(3)A.Around the core,each Fe atom is coordinated by one Cl atom and V atom by three N atoms of CH3CN ligands." @default.
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- W1018173698 date "2001-01-01" @default.
- W1018173698 modified "2023-09-28" @default.
- W1018173698 title "Crystal Structure of Complex (Et4N)[VFe3S4Cl3(CH3CN)3]" @default.
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