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- W1020525149 abstract "Linseed oil, a renewable material obtained from the ripened seeds of the flax plant, was conjugated with C. I. Disperse Red 1 to yield a coloured macromolecule in two experimentally-simplistic coupling steps. Firstly, the abundant presence of carbon–carbon double bonds in linseed oil was exploited to introduce carboxylic acid functionality to linseed oil via a thiol-ene reaction between linseed oil and 3-mercaptopropionic acid. C. I. Disperse Red 1 was then grafted to the carboxylic acid units now present via esterification, offering a coloured product in high yields. On average, 39.2% of the carbon–carbon double bonds in each linseed oil molecule were furnished with a C. I. Disperse Red 1 molecule. The remaining carbon–carbon double bonds may therefore be further exploited for chemical crosslinking, ensuring that the product formed is of potential significance as a coloured, bio-based, surface coating product." @default.
- W1020525149 created "2016-06-24" @default.
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- W1020525149 date "2015-12-01" @default.
- W1020525149 modified "2023-10-14" @default.
- W1020525149 title "Dye conjugation to linseed oil by highly-effective thiol-ene coupling and subsequent esterification reactions" @default.
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- W1020525149 doi "https://doi.org/10.1016/j.dyepig.2015.07.023" @default.
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