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• W1023036906 endingPage "361" @default.
• W1023036906 startingPage "273" @default.
• W1023036906 abstract "This chapter discusses the involvement of hydro complexes in reactions, such as the isomerization, oligomerization, hydrosilylation, and hydrogenation of unsaturated hydrocarbons. Hydro complexes of the transition metals have been known for many years. A hydronickel intermediate was postulated in the nickel-catalyzed hydroalumination of alkynes where small amounts of Ni(acac)2 were found to accelerate the rate of cis-hydroalumination. Reduction with Hydrazine method is significant since it was the first one used in the preparation of PtHCl(PEt3)2 from PtCl2(PEt3)2. Protonation of triphenylphosphine, with a variety of acids has been shown to give hydroplatinum complexes. A convenient route for the preparation of a broad range of hydrosilyl platinum complexes is the reaction of the silyl with Pt(C2H4)(PPh3)2 in the absence of solvent. The oxidative addition of H2 to low-valent d8 complexes, such as IrCl(CO)(PPh3)2, is a common synthetic method for dihydro complexes. Hydro complexes of metals of this triad have been prepared by the hydrogenolysis of σ-bonded ligands. The thermolysis of PtC1(COC8H17)(PPh3)2 gives PtHCl(PPh3)2 and octene. The chloroplatinic acid-catalyzed addition of SiC13H to heptene-3 has been used to prepare n-heptyltrichlorosilane in good yield. In the presence of chloroplatinic acid, methylphenylsilane reacts with propylamine to yield either the mono- or disubstituted silane depending on the ratio of the reactants." @default.
• W1023036906 created "2016-06-24" @default.
• W1023036906 creator A5063160832 @default.
• W1023036906 date "1975-01-01" @default.
• W1023036906 modified "2023-09-26" @default.
• W1023036906 title "Organometallic Reactions Involving Hydro-Nickel, -Palladium, and -Platinum Complexes" @default.
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