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- W1024667013 abstract "Reactivity of α-aroylidineketene dithioacetals 2 was investigated to synthesize novel 2-styrylbenzimidazole derivatives 4 and their hydrothiolated product 2-(2-(methylthio)-2-arylethyl)-1H-benzo[d]imidazoles 5 has been reported. Compounds 4 and 5 were synthesized by cyclocondensation of α-aroylidineketene dithioacetals 2 and o-phenylene diamine (OPD) 3 in the presence and absence of copper catalyst respectively. Regioselective one-pot tandem hydrothiolation of olefin functionality in 4 was achieved under AcOH conditions." @default.
- W1024667013 created "2016-06-24" @default.
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- W1024667013 date "2015-09-01" @default.
- W1024667013 modified "2023-09-27" @default.
- W1024667013 title "α-Aroylidineketene dithioacetal chemistry: CuI catalyzed synthesis of 2-styryl benzimidazoles enroute to regioselective hydrothiolation" @default.
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- W1024667013 doi "https://doi.org/10.1016/j.tet.2015.06.008" @default.
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