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- W102571796 abstract "The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated." @default.
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- W102571796 date "1993-04-01" @default.
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- W102571796 title "Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat" @default.
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- W102571796 doi "https://doi.org/10.1007/bf00814132" @default.
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