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- W102584611 abstract "Abstract Internal composition of passive layers (borate buffer pH 9.2, 0.3V/ SCE ) and Electron Stimulated Oxidized (ESO) layers formed on a series of Fe-Cr alloys (5 - 30 at%) was determined during ageing by quantitative AES depth profiling to approach and compare their film growth processes. ESO films were “in-situ” prepared by high (AES) electron irradiation under low oxygen pressures. In both cases, the film growth process seems to result of an outward cations migration (Fe » Cr) under electric field (Cabrera-Mott model). Slow down of growth kinetics occurs beyond a critical chromium bulk concentration of 10-15 at% and may be attributed to an improved efficiency of inner Cr 2 O 3 layers acting like a diffusion barrier for the Fe cations transport." @default.
- W102584611 created "2016-06-24" @default.
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- W102584611 date "2006-01-01" @default.
- W102584611 modified "2023-10-05" @default.
- W102584611 title "Formation and growth processes of electrochemical passive layers (borate medium: pH 9.2) and electron stimulated oxidized films (5.10−6 Pa O2) formed on Fe-Cr alloys" @default.
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- W102584611 doi "https://doi.org/10.1016/b978-044452224-5/50002-0" @default.
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