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• W1030828135 endingPage "78" @default.
• W1030828135 startingPage "57" @default.
• W1030828135 abstract "This chapter discusses all the important interactions of highly reactive divalent carbon derivatives (carbenes, methylenes) and heterocyclic compounds, and the accompanying molecular rearrangements. The most widely studied reactions have been those of dihalocarbenes, particularly dichlorocarbene, and the α-ketocarbenes obtained by photolytic or copper-catalyzed decomposition of diazo compounds, such as diazoacetic ester or diazoacetone. The reactions of carbenes, which are apparently unique in displaying electrophilic character in strongly basic solutions, include substitution, addition to multiple bonds, and co-ordination with lone pairs of electrons to form unstable ylides. Several long-established reactions of pyrroles and indoles involving their ring expansion to pyridines and quinolines, respectively, proceed under conditions that are favorable to the formation of halocarbenes. The reactions of halocarbenes with several six-membered oxygen and sulfur heterocyclics have been presented." @default.
• W1030828135 created "2016-06-24" @default.
• W1030828135 creator A5023058299 @default.
• W1030828135 creator A5074703030 @default.
• W1030828135 date "1964-01-01" @default.
• W1030828135 modified "2023-10-14" @default.
• W1030828135 title "The Reactions of Heterocyclic Compounds with Carbenes" @default.
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• W1030828135 doi "https://doi.org/10.1016/s0065-2725(08)60541-3" @default.

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