Matches in SemOpenAlex for { <https://semopenalex.org/work/W1033238450> ?p ?o ?g. }
- W1033238450 endingPage "371" @default.
- W1033238450 startingPage "362" @default.
- W1033238450 abstract "The ability of reactive oxygen species (ROS) to interact with priority pollutants is crucial for efficient water treatment by photocatalytic advanced oxidation processes (AOPs). However, background compounds in water such as natural organic matter (NOM) can significantly hinder targeted reactions and removal efficiency. This inhibition can be complex, interfering with degradation in solution and at the photocatalyst surface as well as hindering illumination efficiency and ROS production. We developed an analytical model to account for various inhibition mechanisms in catalytic AOPs, including competitive adsorption of inhibitors, scavenging of produced ROS at the surface and in solution, and the inner filtering of the excitation illumination, which combine to decrease ROS-mediated degradation. This model was validated with batch experiments using a variety of ROS producing systems (OH-generating TiO2 photocatalyst and H2O2-UV; (1)O2-generating photosensitive functionalized fullerenes and rose bengal) and inhibitory compounds (NOM, tert-butyl alcohol). Competitive adsorption by NOM and ROS scavenging were the most influential inhibitory mechanisms. Overall, this model enables accurate simulation of photocatalytic AOP performance when one or more inhibitory mechanisms are at work in a wide variety of application scenarios, and underscores the need to consider the effects of background constituents on degradation efficiency." @default.
- W1033238450 created "2016-06-24" @default.
- W1033238450 creator A5000358111 @default.
- W1033238450 creator A5009334246 @default.
- W1033238450 creator A5081251356 @default.
- W1033238450 creator A5083362426 @default.
- W1033238450 date "2015-11-01" @default.
- W1033238450 modified "2023-10-05" @default.
- W1033238450 title "Inhibitory effect of natural organic matter or other background constituents on photocatalytic advanced oxidation processes: Mechanistic model development and validation" @default.
- W1033238450 cites W115615954 @default.
- W1033238450 cites W1893285309 @default.
- W1033238450 cites W1926950498 @default.
- W1033238450 cites W1967211425 @default.
- W1033238450 cites W1970446300 @default.
- W1033238450 cites W1971550188 @default.
- W1033238450 cites W1972348431 @default.
- W1033238450 cites W1987584688 @default.
- W1033238450 cites W1988765421 @default.
- W1033238450 cites W1995782747 @default.
- W1033238450 cites W1998727760 @default.
- W1033238450 cites W1999963980 @default.
- W1033238450 cites W2004760008 @default.
- W1033238450 cites W2006546159 @default.
- W1033238450 cites W2011727188 @default.
- W1033238450 cites W2019552017 @default.
- W1033238450 cites W2022573674 @default.
- W1033238450 cites W2025449499 @default.
- W1033238450 cites W2027396151 @default.
- W1033238450 cites W2051611630 @default.
- W1033238450 cites W2054020889 @default.
- W1033238450 cites W2058061792 @default.
- W1033238450 cites W2065495758 @default.
- W1033238450 cites W2067598786 @default.
- W1033238450 cites W2072665697 @default.
- W1033238450 cites W2076643825 @default.
- W1033238450 cites W2084354104 @default.
- W1033238450 cites W2092746509 @default.
- W1033238450 cites W2107780218 @default.
- W1033238450 cites W2109604844 @default.
- W1033238450 cites W2112311591 @default.
- W1033238450 cites W2131491403 @default.
- W1033238450 cites W2143400799 @default.
- W1033238450 cites W2157237145 @default.
- W1033238450 cites W2165487314 @default.
- W1033238450 cites W2167504062 @default.
- W1033238450 cites W2312675243 @default.
- W1033238450 cites W2315360650 @default.
- W1033238450 cites W2503156518 @default.
- W1033238450 doi "https://doi.org/10.1016/j.watres.2015.07.044" @default.
- W1033238450 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26302091" @default.
- W1033238450 hasPublicationYear "2015" @default.
- W1033238450 type Work @default.
- W1033238450 sameAs 1033238450 @default.
- W1033238450 citedByCount "113" @default.
- W1033238450 countsByYear W10332384502016 @default.
- W1033238450 countsByYear W10332384502017 @default.
- W1033238450 countsByYear W10332384502018 @default.
- W1033238450 countsByYear W10332384502019 @default.
- W1033238450 countsByYear W10332384502020 @default.
- W1033238450 countsByYear W10332384502021 @default.
- W1033238450 countsByYear W10332384502022 @default.
- W1033238450 countsByYear W10332384502023 @default.
- W1033238450 crossrefType "journal-article" @default.
- W1033238450 hasAuthorship W1033238450A5000358111 @default.
- W1033238450 hasAuthorship W1033238450A5009334246 @default.
- W1033238450 hasAuthorship W1033238450A5081251356 @default.
- W1033238450 hasAuthorship W1033238450A5083362426 @default.
- W1033238450 hasConcept C107872376 @default.
- W1033238450 hasConcept C127413603 @default.
- W1033238450 hasConcept C150394285 @default.
- W1033238450 hasConcept C161790260 @default.
- W1033238450 hasConcept C178790620 @default.
- W1033238450 hasConcept C183696295 @default.
- W1033238450 hasConcept C185592680 @default.
- W1033238450 hasConcept C2777807096 @default.
- W1033238450 hasConcept C2778004101 @default.
- W1033238450 hasConcept C2779679103 @default.
- W1033238450 hasConcept C2780898351 @default.
- W1033238450 hasConcept C2992443382 @default.
- W1033238450 hasConcept C41008148 @default.
- W1033238450 hasConcept C48349386 @default.
- W1033238450 hasConcept C55493867 @default.
- W1033238450 hasConcept C65165184 @default.
- W1033238450 hasConcept C75473681 @default.
- W1033238450 hasConcept C76155785 @default.
- W1033238450 hasConcept C82685317 @default.
- W1033238450 hasConceptScore W1033238450C107872376 @default.
- W1033238450 hasConceptScore W1033238450C127413603 @default.
- W1033238450 hasConceptScore W1033238450C150394285 @default.
- W1033238450 hasConceptScore W1033238450C161790260 @default.
- W1033238450 hasConceptScore W1033238450C178790620 @default.
- W1033238450 hasConceptScore W1033238450C183696295 @default.
- W1033238450 hasConceptScore W1033238450C185592680 @default.
- W1033238450 hasConceptScore W1033238450C2777807096 @default.
- W1033238450 hasConceptScore W1033238450C2778004101 @default.
- W1033238450 hasConceptScore W1033238450C2779679103 @default.
- W1033238450 hasConceptScore W1033238450C2780898351 @default.
- W1033238450 hasConceptScore W1033238450C2992443382 @default.