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- W1034331063 abstract "Corrosion of organic polymer-coated steel involves the formation of a corrosion cell consisting of the metal substrate, water, oxygen, and a layer of conducting electrolyte in contact with both reaction sites.1,2 initially the anodic and cathodic reactions occur at proximate sites (Fig. 1A). The principal reactions are the anodic oxidation of the iron and the cathodic reduction of oxygen. As the corrosion product forms and oxygen and electrolyte concentration gradients are established, the reaction sites separate and localize (Fig. IB). Finally, as the volume of corrosion product increases, the site of the cathodic reaction shifts to the periphery, leading to an increase in the local pH, and through several possible mechanisms, to a loss of adhesion of the polymer coating, thereby propagating coating failure (Fig. 1C). The proposed mechanisms for this cathodic disbonding invoke chemical attack of the coating3 or metal oxide,4 attack of a metal/polymer interphase,5 or alteration of the surface energy of the metal.6 Two extensive reviews of the mechanism are available.7, 8" @default.
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- W1034331063 date "1989-01-01" @default.
- W1034331063 modified "2023-10-13" @default.
- W1034331063 title "In-Situ Measurement of Cathodic Disbonding of Polybutadiene Coating on Steel" @default.
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- W1034331063 doi "https://doi.org/10.1007/978-1-4613-0791-4_14" @default.
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