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- W1034695686 abstract "The phase transition to perovskite-type structure, that occurs in some hexagonal manganites when foreign cations are incorporated into solid solution, has been studied. Several solid solution series belonging to the Y(Mn, Ni)O 3 , (Er, Ca)MnO 3 , (Y, Ca)MnO 3 , systems have been prepared by solid state reaction between the corresponding oxides. The crystalline structure of the different solid solutions has been established. The behaviour of the (Gd, Ca)MnO 3 system has been taken as a reference. The obtained results are discussed as a function of the tolerance factor and the Mn 3+ /Mn 4+ ratio. The transition to perovskite structure is governed by this Mn 3+ /Mn 4+ ratio rather than the increase of the tolerance factor." @default.
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- W1034695686 date "1999-10-01" @default.
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- W1034695686 title "Phase transitions induced on hexagonal manganites by the incorporation of aliovalent cations on A or B lattice sites" @default.
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