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- W1034719147 abstract "A new octanuclear V-S-Cu cluster {V2S6Cu6}(PPh3)6(O)2(2CH2Cl2(CH3OH 1 has been prepared by extraction with CH2Cl2 of a solid mixture of (NH4)3VS4, Cu(PPh3)2Cl and NEt4Br, and its structure has been determined by single-crystal X-ray diffraction. Crystallographic data: C111H98Cl4Cu6O3P6S6V2, Mr = 2248.99, triclinic space group P ī, a = 13.751(6), b = 15.509(4), c = 15.642(5) ?, ( =114.34(2), ( = 98.35(3), ( = 110.43(3) (, V = 2679.83 ?3, Z = 1, Dc = 1.538 g/cm3, F(000) = 1262, ( (MoK() = 16.9 cm－1, the final R = 0.079 and Rw = 0.083 for 5504 observed reflections with I > 2((I). The structural determination shows that the skeleton can be described as a metal-sulfur dodecahedral cage fused by two incomplete cubane-like [VS3Cu3] subunits centrosymmetrically connected by Cu-S and weak Cu-Cu bonds. The six copper and two vanadium atoms display a slightly distorted cubic array with a (4-S atom on each face of the metal cube. The selected IR, electronic and 51V NMR spectra have also been reported." @default.
- W1034719147 created "2016-06-24" @default.
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- W1034719147 date "2001-01-01" @default.
- W1034719147 modified "2023-09-24" @default.
- W1034719147 title "Synthesis,Crystal Structure and Spectroscopic Properties of an Octanuclear V—S—Cu Cluster {V2S6Cu6}（PPh3）6（O）2·2CH2Cl2·CH3OH with a Metal—sulfur Dodecahedral Cage" @default.
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