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- W1035785393 abstract "In acidic medium,thorium(Ⅳ） can react with a bisazo dye of chromotropic acids such as arsenazo Ⅲ(AA Ⅲ） ,arsenazo M(AAM)，chlorophosphonazo Ⅲ(CPA Ⅲ） and chlorosulphonphenol S (CSP S) to form an anionic chelate which further interacts with some proteins to produce a complex.This results in a significant enhancement of intensity of the resonance Rayleigh scattering (RRS) and the appearance of a new RRS spectrum.There are a few obvious RRS peaks in the range of 400-470nm and the most intensive peak of them is located at 470nm.The intensity of RRS is directly proportional to the concentration of protein in the range of 0-1.6μg·mL^-1 for Th(Ⅳ）-CPA Ⅲ system ,0-2.8μg·mL^-1 for Th(Ⅳ）-AA M system,0-2.0μg·mL^-1 for Th (IV)-AAⅢ system and 0-0.28μg·mL^-1 for Th(Ⅳ）-CSP S system,respectively,The detection limits for BSA(3σ) are 10.7 ng·mL^-1 for Th(Ⅳ）-CPA Ⅲ,6.3ng·mL^-1 for Th(Ⅳ）-CSP S，13.6ng·mL^-1 for Th(Ⅳ）-AA Ⅲand 22.1ng·mL^-1 for Th(Ⅳ）-AA M,respectively.This new RRS method has high sensitivity and fairly good selectivity and can be applied to the direct determination of proteins in human serum with satisfactory results." @default.
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- W1035785393 date "2003-01-01" @default.
- W1035785393 modified "2023-09-24" @default.
- W1035785393 title "Resonance Rayleigh Scattering Spectra of Thorium(IV）-bisazo Dye of Chromotropic Acid-protein Systems and Their Analytical Applications" @default.
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