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- W1036195083 abstract "Abstract The complex species formed between vanadium(III)–salicylic acid (H2sal) and the small blood serum bioligands: lactic (Hlac), oxalic (H2ox), citric (H3cit) and phosphoric (H3PO4) acids in aqueous solution were studied by means of electromotive force measurements emf (H) at 25 °C and 3.0 mol·dm− 3 KCl as ionic medium. Data analysis using the least-squares program LETAGROP taking into account the hydrolytic products of vanadium(III) and the formed binaries complexes indicated the formation of V(sal)(lac) complexes, [V(sal)(lac)(OH)]− and [V(sal)(lac)(OH)2]2 − in the vanadium(III)–H2sal–Hlac system. Species V(sal)(Hox)+, [V(sal)(ox)]− were also detected. [V(sal)(ox)(OH)]2 −, [V(sal)2(ox)]3 − and [V(sal)(ox)2]3 − were observed in the vanadium(III)–H2sal–H2ox system; the complexes V(sal)(H2cit), [V(sal)(Hcit)]−, [V(sal)(cit)]2 − and [V(sal)(cit)(OH)]3 − in the vanadium(III)–H2sal–H3cit system and the species V(sal)(H2PO4), [V(sal)(HPO4)]− and [V(sal)(PO4)]2 − were detected in the vanadium(III)–H2sal–H3PO4 system. The corresponding stability constants were estimated." @default.
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- W1036195083 date "2015-11-01" @default.
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- W1036195083 title "Ternary complex formation between vanadium(III) salicylic acid and small blood serum bioligands" @default.
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- W1036195083 doi "https://doi.org/10.1016/j.molliq.2015.05.004" @default.
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