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• W1042001061 abstract "Why is the study of organics on surfaces important? First, metal surfaces have long been known to promote certain organic reactions. These reactions can produce long-lived surface intermediates which can be studied by various techniques, including SIMS and FABMS. Another reason for studying organics on surfaces is based on the pioneering work of BENNINGHOVEN, where it was shown that large involatile organic molecules could be adsorbed and subsequently sputtered nearly intact [1]. This allowed the easy study of these large molecules by mass spectrometry. In the first case mentioned above, the adsorbed species undergo reactions to form different surface compounds. In the second case, one would like the initially adsorbed species and the surface species to remain essentially identical,so that the surface (and bombarding particle) during SIMS and FABMS act simply as a vehicle for obtaining gas phase ions. In both cases, however, one would like the detected ions (both parent and fragments) to be indicative of what was on the surface. It is this requirement that makes the study of what happens to the surface plus adsorbed species during the bombardment process very important.KeywordsPrimary ParticleAdsorbed SpeciesSurface SpeciesBenzene MoleculeClassical DynamicThese keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves." @default.
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• W1042001061 date "1986-01-01" @default.
• W1042001061 modified "2023-09-27" @default.
• W1042001061 title "Mechanisms of Organic Molecule Ejection in SIMS and FABMS" @default.
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• W1042001061 doi "https://doi.org/10.1007/978-3-642-82724-2_123" @default.
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