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- W105409308 abstract "Metallation of [Cr(η6-C6H5NMe2)(CO)3] affords, after subsequent quenching with [Ti(η5-C5H5)2Cl2], the σ,π-bimetallic complex [Cr(η6-C6H5NMe2{TiCp2Cl})(CO)3] in a ratio of 1:3 for the p(1):m(2) isomers. The isomers were separated and 2 crystallizes in the space group Pbca (No. 61), the lattice parameters being a = 14.233(2), b = 15.778(2), c = 17.974(2) Å and Z = 8. The substituents cause a decrease in the endocyclic angles within the benzene ring and the Ti–C(arene) and N–C(arene) bonds are 2.236(5) and 1.378(7) Å, respectively which are indicative of electron donating groups. This is supported by the chemical shifts for the arene resonances in the 1H and 13C NMR spectra. The cyclopentadienyl rings in 2 are diastereotopic due to the planar chirality of the π-complex and the central chirality of the titanium." @default.
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- W105409308 date "1999-01-01" @default.
- W105409308 modified "2023-09-26" @default.
- W105409308 title "π-Arene complexes" @default.
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- W105409308 doi "https://doi.org/10.1016/s0020-1693(98)00275-8" @default.
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