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- W105622663 endingPage "162" @default.
- W105622663 startingPage "117" @default.
- W105622663 abstract "This review covers the literature on reactions of CO2, isoelectronic molecules, like carbonyl sulfide COS, and carbon disulfide CS2, and other heterocumulenes, like isocyanates and isothiocyanates, with aminosilanes and hydridosilanes, that is, compounds with Si–N and Si–H units. The state of the art in this field is compared with our own investigations. In many cases, the CO2 insertions into SiN bonds proceed exothermically providing good to very good yields of the products. In some cases, the insertion reactions have been reported to be reversible, while in other cases, stable and useful products are obtained that have diverse applications in industry, for example, as RTVs (room temperature vulcanizers), for the synthesis of siloxanes, N,N′-disubstituted ureas or isocyanates. Reactions of CS2 and COS with Si–N and Si–H units provide mono-insertion products as well. Isocyanates do not result in the SiO-bonded compounds but SiN moieties are formed. The latter products obtained from isocyanates and isothiocyanates can be utilized as modifiers or precursors for polymers, hybrid, and ceramic materials." @default.
- W105622663 created "2016-06-24" @default.
- W105622663 creator A5001920480 @default.
- W105622663 creator A5018376399 @default.
- W105622663 creator A5035520652 @default.
- W105622663 creator A5037436744 @default.
- W105622663 date "2014-01-01" @default.
- W105622663 modified "2023-09-27" @default.
- W105622663 title "Reactions of CO2 and CO2 Analogs (CXY with X, Y=O, S, NR) with Reagents Containing Si–H and Si–N Units" @default.
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