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- W106985461 endingPage "905" @default.
- W106985461 startingPage "857" @default.
- W106985461 abstract "This chapter consists of an update (1995–2006) of the ring systems described in CHEC-II(1996) (Chapter 6.09) and CHEC(1984) (Chapter 2.26). 1,4-Dioxins, oxathiins, dithiins, and their benzo derivatives, that is, 1,4-benzodioxanes, 1,4-benzoxathiins, and 1,4-benzodithiins, as well as their saturated analogs and the dibenzo derivatives are considered. After a brief introduction on the nomenclature of these heterocycles, theoretical and experimental structural methods are discussed with some thermodynamic aspects. The reactivity of the fully and nonconjugated rings are reported in terms of unimolecular thermal and photochemical reactions, electrophilic attack at carbon and sulfur, nucleophilic attack at hydrogen and sulfur. Reactions with carbenoid, electron-deficient species or going through a cyclic transition state with a second molecule are touched on. The sections enitled heterocycle ring synthesis from acyclic compounds or by transformation of another ring give an overview of the approaches reported in the recent literature. Numerous reactions implicating substituents on the heterocycles are also reported. Finally, a brief section deals with the most important compounds and their applications in organic chemistry or medicinal chemistry." @default.
- W106985461 created "2016-06-24" @default.
- W106985461 creator A5005831943 @default.
- W106985461 creator A5088160200 @default.
- W106985461 date "2008-01-01" @default.
- W106985461 modified "2023-10-17" @default.
- W106985461 title "1,4-Dioxins, Oxathiins, Dithiins, and their Benzo Derivatives" @default.
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