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- W107730034 abstract "The morphology of incompatible polymer blends are often stabilized by the addition of block copolymers that ideally will localize to the polymer-polymer interface and reduce the interfacial tension. However, the effectiveness of adding copolymer is significantly reduced by the tendency of the diblock to form micelles that become trapped within one of the phases. Recent theoretical and experimental results show that using compatibilizers in confined physical geometry will reduce the configurational entropy of the diblock and make it energetically more favorable for the diblock to locate to the interface [1]. Dynamics studies with Scanning Transmission X-ray Microscopy (STXM) show two regimes in the dynamical process, where growth regimes are characterized by growth exponents, α, where R(t)∼Rαt. The first growth regime consists of round micelle-like domain formation and relatively fast growth (α=2/3) of these structures within the PS layer. The second regime results in a relatively stable bicontinuous domain formation with slow growth (α=1/20)." @default.
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- W107730034 date "2000-01-01" @default.
- W107730034 modified "2023-09-24" @default.
- W107730034 title "Compatibilization dynamics in highly immiscible polymer blends" @default.
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- W107730034 doi "https://doi.org/10.1063/1.1291157" @default.
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