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- W108748106 abstract "Adsorption isotherms of binary and ternary mixtures of CO2, ethylene and ethane have been experimentally obtained on a commercial carbon molecular sieve 5A, CMS, (up to 1500 kPa) and on a commercial 5A zeolite (up to 3000 kPa) at 293 K. Some strong equilibrium displacement effects and large deviations from ideal behaviour (including azeotropes) were observed on the adsorption on 5A zeolite, whereas the CMS does not show this behavior. This difference between both adsorbents can be explained in terms of their structure and chemical compositions. Moreover, the equilibrium data have been reproduced and predicted by thermodynamic models like IAS, HIAS, RAS and SPD, modified by introducing fugacity coefficients in the Raoult’s law. The results obtained by RAS and SPD models are practically similar and better than the other ones, particularly for the non-ideal systems on 5A zeolite." @default.
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- W108748106 date "1996-01-01" @default.
- W108748106 modified "2023-09-29" @default.
- W108748106 title "Binary and Ternary Adsorption Equilibria at High Pressure on Molecular Sieves" @default.
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- W108748106 doi "https://doi.org/10.1007/978-1-4613-1375-5_17" @default.
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