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- W109179614 abstract "The reactions of [IrCl(Bu2tPH)3] (1) with the metal carbonyls [M3(CO)12] (M = Fe, Ru) in refluxing toluene have been investigated. By using [Ru3(CO)12] the metal cluster [Ru3(CO)8(μ-H)2(μ3-PBut)(Bu2tPH)] (2) and the butterfly configured heterometallic cluster [Ru3Ir(CO)7(μ-H)2(μ-PBu2t)2(Bu2tPH)(μ3-Cl)] (3) were obtained. On the contrary, the reaction of 1 with [Fe3(CO)12] leads under cluster degradation beside the mononuclear complex [Fe(CO)4(Bu2tPH)] (5) to the known compound [FeIr(μ-CO)(CO)4(μ-PBu2t)(Bu2tPH)] (4) in good yields. The molecular structures of 2 and 3 have been determined by single crystal X-ray studies." @default.
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- W109179614 date "1997-03-01" @default.
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- W109179614 title "Reactions of [IrCl(Bu2tPH)3] with [M3(CO)12](M = Fe, Ru): synthesis and X-ray crystal structures of the metal clusters [Ru3(CO)8(μ-H)2(μ3-PBut)(Bu2tPH)] and [Ru3Ir(CO)7(μ-H)2(μ-PBu2t)2(Bu2tPH)(μ3-Cl)]" @default.
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- W109179614 doi "https://doi.org/10.1016/s0022-328x(96)06685-5" @default.
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