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- W1098958293 abstract "Redox series of the complexes [Ru(L)(L')2](n), L = 1,5-diphenyl-3-(4-tolyl)-formazanate and L' = 2,4-pentanedionate (acac(-)), 2,2'-bipyridine (bpy), or 2-phenylazopyridine (pap), were studied by cyclic and differential pulse voltammetry and by TD-DFT-supported spectroelectrochemistry (UV-vis-NIR, EPR). The precursors [Ru(III)(L(-))(acac(-))2], [Ru(II)(L(-))(bpy)2]ClO4, and [Ru(II)(L(-))(pap)2]ClO4 were identified in their indicated oxidation states by X-ray crystal structure determination. The six-membered formazanato-ruthenium chelate rings have an envelope conformation with puckering of the metal. DFT calculations indicate a pronounced sensitivity of the N-N bond lengths toward the ligand oxidation state. Several electrochemically accessible charge states were analyzed, and the derived oxidation numbers Ru(II), Ru(III), or Ru(IV), L' or (L')(•-), and L(-), L(•2-), or the new formazanyl ligand L(•) for the two-way noninnocent formazanate reflect the increasing acceptor effect of the ancillary ligands L' in the series acac(-) < bpy < pap." @default.
- W1098958293 created "2016-06-24" @default.
- W1098958293 creator A5007237862 @default.
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- W1098958293 creator A5010099982 @default.
- W1098958293 creator A5020043051 @default.
- W1098958293 creator A5062826786 @default.
- W1098958293 date "2015-08-05" @default.
- W1098958293 modified "2023-10-16" @default.
- W1098958293 title "Evidence for Bidirectional Noninnocent Behavior of a Formazanate Ligand in Ruthenium Complexes" @default.
- W1098958293 cites W1558033331 @default.
- W1098958293 cites W1629179716 @default.
- W1098958293 cites W1963824403 @default.
- W1098958293 cites W1965315995 @default.
- W1098958293 cites W1970225878 @default.
- W1098958293 cites W1977935357 @default.
- W1098958293 cites W1978303107 @default.
- W1098958293 cites W1980174287 @default.
- W1098958293 cites W1981624252 @default.
- W1098958293 cites W1981975284 @default.
- W1098958293 cites W1987141277 @default.
- W1098958293 cites W1989393950 @default.
- W1098958293 cites W1990501022 @default.
- W1098958293 cites W1991392023 @default.
- W1098958293 cites W1991554618 @default.
- W1098958293 cites W1993396461 @default.
- W1098958293 cites W1999832496 @default.
- W1098958293 cites W2000009810 @default.
- W1098958293 cites W2001465174 @default.
- W1098958293 cites W2011227483 @default.
- W1098958293 cites W2015723183 @default.
- W1098958293 cites W2020860121 @default.
- W1098958293 cites W2021616354 @default.
- W1098958293 cites W2023271753 @default.
- W1098958293 cites W2024812092 @default.
- W1098958293 cites W2028359120 @default.
- W1098958293 cites W2030175511 @default.
- W1098958293 cites W2034364636 @default.
- W1098958293 cites W2035544689 @default.
- W1098958293 cites W2036669541 @default.
- W1098958293 cites W2037832728 @default.
- W1098958293 cites W2039559098 @default.
- W1098958293 cites W2041337397 @default.
- W1098958293 cites W2041548440 @default.
- W1098958293 cites W2043194193 @default.
- W1098958293 cites W2048158093 @default.
- W1098958293 cites W2058848030 @default.
- W1098958293 cites W2063663126 @default.
- W1098958293 cites W2068228867 @default.
- W1098958293 cites W2068653312 @default.
- W1098958293 cites W2069197437 @default.
- W1098958293 cites W2075064996 @default.
- W1098958293 cites W2075734354 @default.
- W1098958293 cites W2076436210 @default.
- W1098958293 cites W2076834406 @default.
- W1098958293 cites W2076940601 @default.
- W1098958293 cites W2077930487 @default.
- W1098958293 cites W2083481223 @default.
- W1098958293 cites W2086579657 @default.
- W1098958293 cites W2088791877 @default.
- W1098958293 cites W2089497781 @default.
- W1098958293 cites W2106746112 @default.
- W1098958293 cites W2107055594 @default.
- W1098958293 cites W2107526026 @default.
- W1098958293 cites W2109122627 @default.
- W1098958293 cites W2114918609 @default.
- W1098958293 cites W2121045793 @default.
- W1098958293 cites W2121241715 @default.
- W1098958293 cites W2122078186 @default.
- W1098958293 cites W2122444905 @default.
- W1098958293 cites W2128609097 @default.
- W1098958293 cites W2130852920 @default.
- W1098958293 cites W2131350133 @default.
- W1098958293 cites W213791877 @default.
- W1098958293 cites W2138441378 @default.
- W1098958293 cites W2155444290 @default.
- W1098958293 cites W2158683289 @default.
- W1098958293 cites W2161922877 @default.
- W1098958293 cites W2164924181 @default.
- W1098958293 cites W2166734608 @default.
- W1098958293 cites W2170921936 @default.
- W1098958293 cites W2316426893 @default.
- W1098958293 cites W2320482508 @default.
- W1098958293 cites W2322007817 @default.
- W1098958293 cites W2323842452 @default.
- W1098958293 cites W2329223867 @default.
- W1098958293 cites W2332640690 @default.
- W1098958293 cites W2333842792 @default.
- W1098958293 cites W2950681919 @default.
- W1098958293 cites W3137112198 @default.
- W1098958293 cites W4237931903 @default.
- W1098958293 cites W4255748067 @default.
- W1098958293 cites W1934541135 @default.
- W1098958293 doi "https://doi.org/10.1021/acs.inorgchem.5b01408" @default.
- W1098958293 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26244848" @default.
- W1098958293 hasPublicationYear "2015" @default.
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