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• W110355756 endingPage "621" @default.
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• W110355756 abstract "Recent advances in the synthesis, characterization, reactivity, and applications of four-membered heterocyclic ring systems comprised of one boron or transition metal atom are reviewed. The published literature since 1993 is reviewed comprehensively, with sufficient references to earlier work to construct a coherent and accurate narrative. Coverage includes both theoretical (computational) and experimental investigations, including significant structural parameters, crystallographic and spectroscopic data, and thermodynamic factors relevant to this structural class. The synthesis and reactivity of boracyclobutane, metallacyclobutane, boracyclobutene, metallacyclobutene, and metallacyclobutadiene compounds constitute the principal focus of the review. The synthetic literature is categorized by reaction type, with significant subsections devoted to the [2+2] cycloaddition of metal alkylidene complexes with alkenes or alkynes, transmetallation methodology, cyclization by γ-hydrogen elimination reaction, oxidative carbon–carbon bond activation of cyclopropane derivatives, ring contractions and ring expansions of larger and smaller metallacycles, and central carbon alkylation of transition metal η3-allyl and η3-propargyl/allenyl complexes. Developments in the latter area have been most substantial and are discussed in the greatest detail. The reactivity of each structural subclass is further divided in terms of thematic content: protonolysis of the organic fragment, transmetallation, migratory insertion of small unsaturated molecules (CO, alkenes, alkynes, etc.), [2+2] cycloreversion to produce metal alkylidene and alkylidyne complexes, cyclopropanation, β-hydrogen elimination, and other structural isomerizations and rearrangements. Significant applications to organic synthesis are also discussed, explicitly excluding the thoroughly reviewed area of alkene (and alkyne) metathesis. Both stoichiometric and catalytic applications are reviewed, as is the prognosis for further developments of utility in organic synthesis and materials chemistry." @default.
• W110355756 created "2016-06-24" @default.
• W110355756 creator A5008685134 @default.
• W110355756 creator A5023581754 @default.
• W110355756 creator A5055972963 @default.
• W110355756 date "2008-01-01" @default.
• W110355756 modified "2023-09-24" @default.
• W110355756 title "Four-membered Rings with One Boron or Other Atom" @default.
• W110355756 cites W1493104024 @default.
• W110355756 cites W1534150946 @default.
• W110355756 cites W1909661963 @default.
• W110355756 cites W1963681117 @default.
• W110355756 cites W1964426486 @default.
• W110355756 cites W1964725136 @default.
• W110355756 cites W1964745319 @default.
• W110355756 cites W1965254908 @default.
• W110355756 cites W1966492274 @default.
• W110355756 cites W1966778250 @default.
• W110355756 cites W1967227134 @default.
• W110355756 cites W1967611769 @default.
• W110355756 cites W1967637833 @default.
• W110355756 cites W1967949659 @default.
• W110355756 cites W1968166527 @default.
• W110355756 cites W1968296833 @default.
• W110355756 cites W1968942534 @default.
• W110355756 cites W1969229551 @default.
• W110355756 cites W1969558046 @default.
• W110355756 cites W1970213000 @default.
• W110355756 cites W1970267116 @default.
• W110355756 cites W1970920593 @default.
• W110355756 cites W1971248073 @default.
• W110355756 cites W1971932112 @default.
• W110355756 cites W1972756549 @default.
• W110355756 cites W1973114006 @default.
• W110355756 cites W1973135416 @default.
• W110355756 cites W1973376996 @default.
• W110355756 cites W1974000953 @default.
• W110355756 cites W1974050064 @default.
• W110355756 cites W1974590627 @default.
• W110355756 cites W1974793154 @default.
• W110355756 cites W1975210960 @default.
• W110355756 cites W1976483790 @default.
• W110355756 cites W1976894600 @default.
• W110355756 cites W1976973527 @default.
• W110355756 cites W1977520273 @default.
• W110355756 cites W1979076308 @default.
• W110355756 cites W1979839606 @default.
• W110355756 cites W1982380474 @default.
• W110355756 cites W1982485023 @default.
• W110355756 cites W1985280098 @default.
• W110355756 cites W1987505018 @default.
• W110355756 cites W1988239179 @default.
• W110355756 cites W1988527017 @default.
• W110355756 cites W1988772002 @default.
• W110355756 cites W1988789709 @default.
• W110355756 cites W1988989333 @default.
• W110355756 cites W1989799279 @default.
• W110355756 cites W1990224747 @default.
• W110355756 cites W1990391514 @default.
• W110355756 cites W1990728404 @default.
• W110355756 cites W1990886182 @default.
• W110355756 cites W1991025349 @default.
• W110355756 cites W1991301071 @default.
• W110355756 cites W1991950466 @default.
• W110355756 cites W1992450122 @default.
• W110355756 cites W1992943872 @default.
• W110355756 cites W1992960426 @default.
• W110355756 cites W1992975884 @default.
• W110355756 cites W1993783705 @default.
• W110355756 cites W1994665484 @default.
• W110355756 cites W1995369926 @default.
• W110355756 cites W1996452574 @default.
• W110355756 cites W1996742069 @default.
• W110355756 cites W1996830652 @default.
• W110355756 cites W1996911930 @default.
• W110355756 cites W1997296078 @default.
• W110355756 cites W1998641801 @default.
• W110355756 cites W1999942204 @default.
• W110355756 cites W2000011279 @default.
• W110355756 cites W2000181508 @default.
• W110355756 cites W2000487620 @default.
• W110355756 cites W2001113145 @default.
• W110355756 cites W2001593230 @default.
• W110355756 cites W2001693653 @default.
• W110355756 cites W2001920652 @default.
• W110355756 cites W2002067802 @default.
• W110355756 cites W2003003856 @default.
• W110355756 cites W2003315407 @default.
• W110355756 cites W2003406126 @default.
• W110355756 cites W2004466325 @default.
• W110355756 cites W2004736708 @default.
• W110355756 cites W2004773906 @default.
• W110355756 cites W2004952626 @default.
• W110355756 cites W2005166635 @default.
• W110355756 cites W2005710968 @default.
• W110355756 cites W2005972113 @default.
• W110355756 cites W2006700420 @default.
• W110355756 cites W2006804670 @default.

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