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- W1104828769 abstract "This paper presents the new highly selective iridium-catalyzed hydroformylation of 1-octene with an Ir(cod)(acac)/PPh3/salt catalyst system. The addition of inorganic salts such as LiCl suppresses the hydrogenation of 1-octene and increases the yield of desired hydroformylation products. Even low amounts of LiCl (LiCl/Ir = 2/1) significantly increase the chemoselectivity of aldehydes up to 94% with a 1-octene conversion of 90% within 7 h. This catalyst is applicable to other alkenes such as 1-pentene or 1-dodecene. The high selectivities and the remarkable activity of the optimized iridium catalyst are promising in terms of successfully implementing on an industrial scale in the future." @default.
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- W1104828769 date "2015-09-01" @default.
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- W1104828769 title "Crucial role of additives in iridium-catalyzed hydroformylation" @default.
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- W1104828769 doi "https://doi.org/10.1016/j.apcata.2015.08.001" @default.
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