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- W11056380 abstract "This paper records the process of the interconversion of enantiomeric tetrahedral structures by the dynamic-NMR method for inner-complex compounds with a chelate entity of NiN/sub 2/X/sub 2/ (X = S, Se), namely systematic series of bis(4-(iminomethyl)pyrazole-5-thiolato(selenolato) )nickels. The values of the activation barriers to interconversion are determined by the steric structure of the substituents on the coordinated nitrogen tom and increase with rise in the steric hindrance in the planar form of the complexes, which indicates that the reaction goes by the diagonal-twist mechanism." @default.
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- W11056380 date "1985-10-10" @default.
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- W11056380 title "Inversion of configuration of tetrahedral BIS(4-(iminomethyl)pyrazole-5-thiolato(selenolato) nickels" @default.
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