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- W110653570 abstract "Polyfluorinated 1,3- and 1,4-cyclohexadienes are fluorinated by vanadium fluoride at /minus/25 to +25/degree/C. The olefinic fragments of perfluoro-1,3- and perfluoro-1,4-cyclohexadienes are close to each other in reactivity. Under the influence of vanadium pentafluoride the fluorine atoms add to 1-R-haptafluoro-1,4-cyclohexadienes preferentially at the multiple bond containing the less electron-withdrawing substituent. At /minus/80 to +20/degree/C antimony pentafluoride leads to isomerization of the polyfluorinated derivatives of cyclohexadiene." @default.
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- W110653570 date "1988-12-10" @default.
- W110653570 modified "2023-09-24" @default.
- W110653570 title "Action of vanadium and antimony pentafluorides on polyfluorinated derivatives of cyclohexadinene" @default.
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