Matches in SemOpenAlex for { <https://semopenalex.org/work/W1107079646> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W1107079646 endingPage "169" @default.
- W1107079646 startingPage "164" @default.
- W1107079646 abstract "The [Ga(III)3(3,5-diCl-Sal-AHA)3(μ-OCH3)]− anion crystallizes with one K+ and one H3O+ counter ion between each pair of anions. The structure is analogous to the previously reported [Fe(III)3(3,5-diCl-Sal-AHA)3(μ-OCH3)]−, with each containing a M3O4 incomplete cubane at the base of a phenyl-derived pocket that surrounds a triply bridging methoxy group. The EPR spectrum of [Fe(III)3(3,5-diCl-Sal-AHA)3(μ-OCH3)]− at 4.5 K is complex with features near geff = 2, 4.3, and above 5. Only the 4.30 feature maintains intensity much above 30 K, and it persists to above 150 K. Room temperature magnetic susceptibility measurements indicate an average spin of S = 5/2 per trimer in both solid and solution. Both the Ga and Fe clusters are stable in methanol. However, the Ga complex slowly decomposes in 40% water or in the presence of EDTA, while the Fe cluster does not. Experiments with a mixed Fe/Ga solution show that the order of stability of the [M(III)3(3,5-diCl-Sal-AHA)3(μ-OCH3)]−, clusters in the presence of EDTA is M(III)3 = Fe3 > Fe2Ga > FeGa2 > Ga3. Metal or chelate exchange occurs very slowly (weeks to months) if at all. However, the μ3-methoxy bridge can be replaced by deuterated methoxy or a μ3-hydroxy bridge within hours to days." @default.
- W1107079646 created "2016-06-24" @default.
- W1107079646 creator A5031367983 @default.
- W1107079646 creator A5033225647 @default.
- W1107079646 creator A5040305041 @default.
- W1107079646 creator A5059108304 @default.
- W1107079646 creator A5068552037 @default.
- W1107079646 creator A5071465132 @default.
- W1107079646 date "2015-11-01" @default.
- W1107079646 modified "2023-10-02" @default.
- W1107079646 title "Structure, spectroscopy, stability, and bridge exchange in the M3O4 incomplete-cubane complexes, [M(III)3(Sal-AHA)3(μ-OR)]− (M = Fe, Ga)" @default.
- W1107079646 cites W1985857032 @default.
- W1107079646 cites W1994056831 @default.
- W1107079646 cites W2012301321 @default.
- W1107079646 cites W2015742145 @default.
- W1107079646 cites W2028791480 @default.
- W1107079646 cites W2032978173 @default.
- W1107079646 cites W2033493424 @default.
- W1107079646 cites W2038077864 @default.
- W1107079646 cites W2043950414 @default.
- W1107079646 cites W2046697566 @default.
- W1107079646 cites W2047679766 @default.
- W1107079646 cites W2051271391 @default.
- W1107079646 cites W2057710176 @default.
- W1107079646 cites W2085034303 @default.
- W1107079646 cites W2089867331 @default.
- W1107079646 cites W2095237297 @default.
- W1107079646 cites W2099037802 @default.
- W1107079646 cites W2105499170 @default.
- W1107079646 cites W2125485599 @default.
- W1107079646 cites W2140662708 @default.
- W1107079646 cites W2157986221 @default.
- W1107079646 cites W2316458351 @default.
- W1107079646 cites W2523972351 @default.
- W1107079646 doi "https://doi.org/10.1016/j.poly.2015.07.069" @default.
- W1107079646 hasPublicationYear "2015" @default.
- W1107079646 type Work @default.
- W1107079646 sameAs 1107079646 @default.
- W1107079646 citedByCount "5" @default.
- W1107079646 countsByYear W11070796462017 @default.
- W1107079646 countsByYear W11070796462018 @default.
- W1107079646 countsByYear W11070796462023 @default.
- W1107079646 crossrefType "journal-article" @default.
- W1107079646 hasAuthorship W1107079646A5031367983 @default.
- W1107079646 hasAuthorship W1107079646A5033225647 @default.
- W1107079646 hasAuthorship W1107079646A5040305041 @default.
- W1107079646 hasAuthorship W1107079646A5059108304 @default.
- W1107079646 hasAuthorship W1107079646A5068552037 @default.
- W1107079646 hasAuthorship W1107079646A5071465132 @default.
- W1107079646 hasBestOaLocation W11070796461 @default.
- W1107079646 hasConcept C115624301 @default.
- W1107079646 hasConcept C121332964 @default.
- W1107079646 hasConcept C178790620 @default.
- W1107079646 hasConcept C185592680 @default.
- W1107079646 hasConcept C187961010 @default.
- W1107079646 hasConcept C2776403692 @default.
- W1107079646 hasConcept C2779546866 @default.
- W1107079646 hasConcept C2780750454 @default.
- W1107079646 hasConcept C46141821 @default.
- W1107079646 hasConcept C544153396 @default.
- W1107079646 hasConcept C71240020 @default.
- W1107079646 hasConcept C8010536 @default.
- W1107079646 hasConceptScore W1107079646C115624301 @default.
- W1107079646 hasConceptScore W1107079646C121332964 @default.
- W1107079646 hasConceptScore W1107079646C178790620 @default.
- W1107079646 hasConceptScore W1107079646C185592680 @default.
- W1107079646 hasConceptScore W1107079646C187961010 @default.
- W1107079646 hasConceptScore W1107079646C2776403692 @default.
- W1107079646 hasConceptScore W1107079646C2779546866 @default.
- W1107079646 hasConceptScore W1107079646C2780750454 @default.
- W1107079646 hasConceptScore W1107079646C46141821 @default.
- W1107079646 hasConceptScore W1107079646C544153396 @default.
- W1107079646 hasConceptScore W1107079646C71240020 @default.
- W1107079646 hasConceptScore W1107079646C8010536 @default.
- W1107079646 hasFunder F4320306076 @default.
- W1107079646 hasFunder F4320337480 @default.
- W1107079646 hasLocation W11070796461 @default.
- W1107079646 hasLocation W11070796462 @default.
- W1107079646 hasOpenAccess W1107079646 @default.
- W1107079646 hasPrimaryLocation W11070796461 @default.
- W1107079646 hasRelatedWork W1006345049 @default.
- W1107079646 hasRelatedWork W1993083330 @default.
- W1107079646 hasRelatedWork W2024927936 @default.
- W1107079646 hasRelatedWork W2072260776 @default.
- W1107079646 hasRelatedWork W2084293481 @default.
- W1107079646 hasRelatedWork W2087193027 @default.
- W1107079646 hasRelatedWork W2093367222 @default.
- W1107079646 hasRelatedWork W2306574610 @default.
- W1107079646 hasRelatedWork W2327312814 @default.
- W1107079646 hasRelatedWork W3137930970 @default.
- W1107079646 hasVolume "100" @default.
- W1107079646 isParatext "false" @default.
- W1107079646 isRetracted "false" @default.
- W1107079646 magId "1107079646" @default.
- W1107079646 workType "article" @default.