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• W110740096 abstract "Model isotherms have been calculated for the adsorption of nitrogen and argon at the temperature of their normal boiling points, both for a free surface and for the surface within slit-shaped pores using density functional theory. The calculations incorporate a smoothed density approximation (SDA) for the hard-sphere repulsion terms, and Monte Carlo simulation was used to confirm important aspects of the adsorbate density distribution. Free surface isotherms were tested against experimental isotherms for a non-porous graphite, Sterling FT-G (2700), and surface energy analysis was performed to determine the characteristic gas-solid interaction values. Density functional theory was found to yield a very good description of the adsorption isotherm in the monolayer region; however, the theory in its present form underestimates the pressure at which second and higher layer formation becomes important." @default.
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• W110740096 date "1994-01-01" @default.
• W110740096 modified "2023-10-14" @default.
• W110740096 title "Determination of Pore Size Distribution from Density Functional Theory: A Comparison of Nitrogen and Argon Results" @default.
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• W110740096 doi "https://doi.org/10.1016/s0167-2991(08)63067-0" @default.
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