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- W111558081 abstract "Following Pauling’s analysis (Pauling 1948, 1958), most enzymologists relate enzyme specificity to the supposed geometric complementarity between enzyme and substrate, the structural match being realized either at the initial stage of binding or later during the formation of a transition complex (Koshland 1958; Wolfenden 1972; Fersht 1974; Jencks 1975). The concept of stereochemical complementarity (Fischer 1894), which is fundamental to our understanding of the replication of the genetic material (Pauling and Delbruck 1940; Watson and Crick 1953), was invoked whenever there was a problem of molecular specificity, from immunology (Ehrlich 1900; Haurowitz 1967) to molecular evolution (Woese 1967). Yet there is now a rapidly growing body of knowledge which is being produced and organized along a quite different mode of thinking. The following are a few examples of recent experimental findings which created difficulties for the geometric viewpoint and contributed to the spread of the kinetic ideas." @default.
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- W111558081 date "1980-01-01" @default.
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- W111558081 title "Recognition: the Kinetic Concepts" @default.
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