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- W112088556 abstract "The copper(11)-catalyzed oxidative decarboxylation of aliphatic carboxylic acids proceeds through an initial inner sphere one- or two-electron transfer, yielding a carboxyl radical or cation respectively. The carboxyl radical resulting from one-electron transfer rapidly decarboxylates, after which the aliphatic radical may react with dioxygen -if present- to a ketone, alcohol or aldehyde. This occurs by Cu(1,11) or H+-catalyzed decomposition of the intermediate (hydro) peroxide. The aliphatic radical can also be oxidized by mononuclear Cu(11) to a carbocation, which yields an ester by reaction with a carboxylic acid (anion), or an alkene by p-H elimination. The carboxylate cation, formed by initial two-electron transfer, can perform an electrophilic attack on an x-C of another carboxylic acid, yielding a new carboxylic acid with an ester group. It can also undergo p-H elimination, yielding an alkene carboxylic acid." @default.
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- W112088556 date "1994-01-01" @default.
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- W112088556 title "Copper-catalyzed oxidative decarboxylation of aliphatic carboxylic acids" @default.
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- W112088556 doi "https://doi.org/10.1016/s0167-2991(08)63458-8" @default.
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