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- W112184477 abstract "The angular dependences of the proton, deuteron, and ${mathrm{Na}}^{23}$ magnetic-resonance spectra have been measured as a function of temperature in both normal (STSe) and deuterated (D-STSe) sodium trihydrogen selenite, and the electric field gradient tensors at the sodium and deuteron sites have been determined. These data show that the two ferroelectric transitions in STSe ($frac{2}{m}ensuremath{rightarrow}1ensuremath{rightarrow}m$) are accompanied by a doubling of the unit-cell edges in the $a$ and $b$ directions with respect to the paraelectric unit cell, whereas there is just one transition in D-STSe ($frac{2}{m}ensuremath{rightarrow}m$), which is connected with a doubling in the $b$ direction only. The triclinic ferroelectric phase which exists in STSe between - 79 and - 173ifmmode^circelsetextdegreefi{}C thus does not appear in D-STSe. The transitions are accompanied by an ordering of hydrogens (which in the paraelectric phase are rapidly jumping from one equilibrium site in the H bond to another) as well as by a distortion of the Se${mathrm{O}}_{3}^{ensuremath{-}}$ and ${mathrm{Na}}^{+}$ network." @default.
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- W112184477 date "1968-12-10" @default.
- W112184477 modified "2023-10-17" @default.
- W112184477 title "Nuclear-Magnetic-Resonance Study of the Ferroelectric Transitions in NaH3(SeO3)2and NaD3(SeO3)2" @default.
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- W112184477 doi "https://doi.org/10.1103/physrev.176.732" @default.
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