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- W112603669 abstract "Electrogenerated I (I) in CH/sub 3/COOH against a background of 0.2 M HC10/sub 4/ was used to determine hydroquinone and pyrocatechol (redox reactions), phenol, 0-, p-, and m-cresols, resorcinol, mesitylene, xylenes (electrophilic substitution reactions). The electrogeneration of I (I) was carried out at a current of 4 mA. The titration end point was recorded biamperometrically on two platinum electrodes. In a given medium, o- and p-cresols and o-, m-, and p-xylenes quantitatively react with I (I) to form diiodo derivatives, phenol and I (I) give a triiodo derivative, m-cresol - a tetraiodo derivative, and resorcinol - a pentaiodo derivative. It was concluded that iodine (I) can be used in redox and in halogenation reactions to determine microgram quantities of hydroquinone, pyrocatechol, mesitylene, o-, m-, and p-xylenes, phenol, m- and p-cresols, and resorcinol." @default.
- W112603669 created "2016-06-24" @default.
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- W112603669 date "1986-02-01" @default.
- W112603669 modified "2023-09-24" @default.
- W112603669 title "Electrogeneration of iodine(I) from methyl iodide in acetic acid in coulometric analysis" @default.
- W112603669 hasPublicationYear "1986" @default.
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