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- W1126329298 abstract "This chapter describes the application of reactions of the nitroparaffins to sugar synthesis. Nitroparaffins can be produced economically by the direct nitration of paraffin hydrocarbons in the vapor phase. The chemistry of the nitroparaffins is discussed. The nitromethane synthesis, like the cyanohydrin synthesis, results in the addition of one carbon atom to an aldose carbon chain with the production of the two next higher epimeric aldose sugars. The 2-nitroethanol synthesis adds two carbon atoms to an aldose carbon chain with the production of two ketose sugars epimeric at carbon 3. When the conditions of the nitromethane-aldose condensation reaction, with the exception that nitromethane is replaced by 2-nitroethanol, are applied to D-arabinose, the condensation reaction proceeds with rapid solution of the pentose followed by precipitation of the amorphous sodium aci-nitroalcohols." @default.
- W1126329298 created "2016-06-24" @default.
- W1126329298 creator A5080544712 @default.
- W1126329298 date "1951-01-01" @default.
- W1126329298 modified "2023-10-15" @default.
- W1126329298 title "The Nitromethane and 2-Nitroethanol Syntheses" @default.
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- W1126329298 doi "https://doi.org/10.1016/s0096-5332(08)60071-5" @default.
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