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- W1126557780 abstract "The title compounds, C 13 H 8 ClN 3 O 6 , (I), and C 13 H 9 N 3 O 6 , (II), differ in the orientation of the two aromatic rings. In (I), they are essentially coplanar, making a dihedral angle of 8.2 (1)°, while in (II), they are inclined to one another by 76.2 (1)°. The two nitro groups are essentially coplanar with the attached benzene rings, as indicated by the dihedral angles of 1.4 (2) and 2.3 (2)° in (I), and 4.96 (18) and 5.4 (2)° in (II). The carbamate group is twisted slightly from the attached benzene ring, with a C—N—C—O torsion angle of −170.17 (15)° for (I) and 168.91 (13)° for (II). In the crystals of of both compounds, molecules are linked via N—H...O hydrogen bonds, forming chains propagating along [010]. In (I), C—H...O hydrogen bonds also link molecules within the chains. The crystal packing in (I) also features a very weak π–π interaction [centroid–centroid distance = 3.7519 (9) Å]." @default.
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- W1126557780 date "2015-06-03" @default.
- W1126557780 modified "2023-10-16" @default.
- W1126557780 title "Crystal structures of 4-chlorophenyl<i>N</i>-(3,5-dinitrophenyl)carbamate and phenyl<i>N</i>-(3,5-dinitrophenyl)carbamate" @default.
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- W1126557780 doi "https://doi.org/10.1107/s2056989015010245" @default.
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