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- W1127316574 abstract "Abstract Two lanthanide(III) complexes containing tetraselenidoantimonate ligand [Sm(peha)(μ-1κ 2 :2κ-SbSe 4 )] n ( 1 ), and [Eu(peha)(1κ 2 -SbSe 4 )] ( 2 ) (peha = pentaethylenehexamine) were solvothermally prepared by reactions Sb, Se and LnCl 3 in pentaethylenehexamine (peha). The tetrahedral [SbSe 4 ] 3 − unit connects [Sm(peha)] 3 + into the neutral 1-D coordination polymer 1 as a tridentate μ-1κ 2 :2κ-SbSe4 bridging and chelating ligand. It coordinates to [Eu(peha)] 3 + with a 1κ 2 -SbSe 4 chelating mode, forming the mononuclear complex 2 . The tridentate μ-1κ 2 :2κ-SbSe 4 bridging and chelating mode and 9-coordinate Sm(III) center in 1 are firstly observed in the systematic syntheses of the Sm/Sb/Se system in different polyethylenediamines. Compounds 1 and 2 exhibit steep band gaps at 2.04 and 2.11 eV at room temperature, respectively." @default.
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- W1127316574 date "2015-10-01" @default.
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- W1127316574 title "The first lanthanide–tetraselenidoantimonate complexes with hexadentate polyamine co-ligand: Solvothermal syntheses of [Sm(peha)(SbSe 4 )] n and [Eu(peha)(SbSe 4 )]" @default.
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- W1127316574 doi "https://doi.org/10.1016/j.inoche.2015.08.005" @default.
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