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• W1129730006 endingPage "1228" @default.
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• W1129730006 abstract "Herein, we report the X-ray crystallographic structure of a 38-metal atom Au-Ag alloy nanomolecule. The structure of monometallic Au38(SR)24 consists of 2 central Au atoms and 21 Au atoms forming a bi-icosahedral core protected by 6 dimeric and 3 monomeric units. In Au38-xAgx(SR)24,where x ranges from 1 to 5, the silver atoms are selectively incorporated into the Au21 bi-icosahedral core. Within the Au21 core, the silver atoms preferentially occupy nine selected locations: (a) the two vertex edges, three atoms on each edge and six atoms total, and (b) the middle face-shared three-atom ring, adding to a total of nine locations. X-ray crystallography yielded a composition of Au34.04Ag3.96(SCH2CH2Ph)24. The crystal structure of the alloy nanomolecule can be described in terms of shells as Au2@Au17.04Ag3.96@ 6×[-SR-Au-SR-Au-SR] 3×[-SR-Au-SR-]." @default.
• W1129730006 created "2016-06-24" @default.
• W1129730006 creator A5038931310 @default.
• W1129730006 creator A5076946236 @default.
• W1129730006 creator A5086044340 @default.
• W1129730006 date "2015-03-23" @default.
• W1129730006 modified "2023-10-07" @default.
• W1129730006 title "X-ray Crystal Structure of Au_{38–<i>x</i>}Ag_<i>x</i>(SCH₂CH₂Ph)₂₄ Alloy Nanomolecules" @default.
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• W1129730006 doi "https://doi.org/10.1021/acs.jpclett.5b00270" @default.
• W1129730006 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26262976" @default.
• W1129730006 hasPublicationYear "2015" @default.
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