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- W1132533085 abstract "Abstract: Sodium bis[N-2-oxyphenyl-5-substituted-salicylideneiminato-ONO]ruthenate(III) hemitriethylamine compounds of general formula Na[Ru(N-R-5-X-salim) 2 ]·0.5Et 3 N, where, R = C 6 H 4 O, X = Cl, Br, NO 2 , salim = salicylideneiminato, Et 3 N triethylamine, were synthesized and characterized on the basis of elemental analysis, MALDI-TOF (matrix-assisted laser desorption/ionization/time-of-flight) mass spectra, 1 H NMR (nuclear magnetic resonance), electronic spectra and cyclic voltammograms. Ru(III) is chelated with two O 2 N anionic tridentate Schiff bases derived from 5-X-salicyladehyde and 2-aminophenol. Spectroscopic titrations of the Ru(III) compounds with CT DNA (calf thymus DNA) in the LMCT (ligand metal charge transfer) region have shown moderate intercalation properties of compounds with binding constants K b = 2.06-3.85 × 10 4 M -1 . Electrochemical evidence of intercalative mode of binding is based on the decrease of current and shift of anodic and cathodic peaks towards higher values of potential with µL-increment of CT DNA in Ru(III) compound solution." @default.
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- W1132533085 date "2014-04-28" @default.
- W1132533085 modified "2023-09-26" @default.
- W1132533085 title "Calf Thymus DNA Intercalation by Anionic Ru(III) Complexes Containing Tridentate Schiff Bases Derived from 5-X-Substituted Salicyladehyde and 2-Aminophenol" @default.
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- W1132533085 doi "https://doi.org/10.17265/1934-7375/2014.04.002" @default.
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