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- W1134921301 abstract "The Stark effect is considered for polyatomic open shell complexes that exhibit partially quenched electronic angular momentum. Matrix elements of the Stark Hamiltonian represented in a parity conserving Hund’s case (a) basis are derived for the most general case, in which the permanent dipole moment has projections on all three inertial axes of the system. Transition intensities are derived, again for the most general case, in which the laser polarization has projections onto axes parallel and perpendicular to the Stark electric field, and the transition dipole moment vector is projected onto all three inertial axes in the molecular frame. Simulations derived from this model are compared to experimental rovibrational Stark spectra of OH–C2H2, OH–C2H4, and OH–H2O complexes formed in helium nanodroplets." @default.
- W1134921301 created "2016-06-24" @default.
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- W1134921301 date "2015-08-01" @default.
- W1134921301 modified "2023-10-12" @default.
- W1134921301 title "On the Stark effect in open shell complexes exhibiting partially quenched electronic angular momentum: Infrared laser Stark spectroscopy of OH–C2H2, OH–C2H4, and OH–H2O" @default.
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- W1134921301 doi "https://doi.org/10.1016/j.jms.2015.06.002" @default.
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