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- W114051693 abstract "Effect of transition metal additives on the performance of metal oxide catalysts for the title reaction was investigated. Addition of Mn, Fe, Co, Ni and Cu promoted the activity of alumina at lower temperatures and higher space velocity. The activity of Co/Al2O3 was found to be affected by preparation conditions. The increase in the de-NOx activity could be attributed to the cooperation between alumina and finely dispersed metal species. In contrast to alumina, the addition of Fe and Co decreased the activity of titania whereas V enhanced the de-NOx activity at lower temperatures. Activity enhancement was not observed for zirconia.Catalytic performance of silica and alumina-supported noble metals was also investigated. Pt, Pd and Rh/SiO2 catalysts showed catalytic activity for the NO reduction with propylene. In particular, NO reduction with olefins and aromatic compounds proceeded around 200°C over Pt/SiO2. However, paraffins did not serve as effective reducing agents over Pt, Pd and Rh/SiO2. On the other hand, Pt, Pd and Rh/Al2O3 catalyzed NO reduction with paraffins. This activity could also be ascribed to the cooperation of noble metals and alumina." @default.
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- W114051693 date "1994-01-01" @default.
- W114051693 modified "2023-09-25" @default.
- W114051693 title "Metal additive effect on the performance of metal oxide catalysts for the selective reduction of nitrogen oxides with hydrocarbons" @default.
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- W114051693 doi "https://doi.org/10.1016/b978-1-4832-8381-4.50103-7" @default.
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