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- W114052021 abstract "Desorption of potassium from the industrial iron catalysts for ammonia synthesis and the reference compound KAlO 2 was monitored by surface ionisation detection. Activation energies for desorption are close to each other within the narrow range 1.7–1.8 eV: for KAlO 2 , for Polish industrial catalyst PS3-INS boiled in water and for its precursor kept in moist atmosphere for two years. The coincidence includes also literature values for the industrial catalyst AS-4 deactivated by usage in an industrial reactor for five years. The data obtained confirm the concept by Somorjai that formation of potassium aluminate implies the deactivation of iron catalysts" @default.
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- W114052021 date "1999-01-01" @default.
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- W114052021 title "Deactivation of iron catalyst by water-potassium thermal desorption studies" @default.
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- W114052021 doi "https://doi.org/10.1016/s0167-2991(99)80471-6" @default.
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