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- W1145176075 abstract "New rhodium(III)-triphenylphosphine complex, [Rh(PPh3)(L)Cl2](PF6) (1) with thioether containing NNS donor ligand (L) (L = 2-(methylthio)-N-((pyridine-2-yl)methylene)benzenamine) has been synthesized and characterized. The pseudo octahedral geometry of the complex has been confirmed by single crystal X-ray analysis. The electronic structure, redox properties, absorption and emission properties of the complexes have been interpreted by DFT and TDDFT calculations. The complex effectively catalyzed the transfer hydrogenation reaction of ketones in 2-propanol and oxidation of alcohols in presence of NMO." @default.
- W1145176075 created "2016-06-24" @default.
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- W1145176075 date "2015-11-01" @default.
- W1145176075 modified "2023-10-13" @default.
- W1145176075 title "Rhodium(III)-triphenylphosphine complex with NNS donor thioether containing Schiff base ligand: Synthesis, spectra, electrochemistry and catalytic activity" @default.
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- W1145176075 doi "https://doi.org/10.1016/j.molstruc.2015.06.065" @default.
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