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- W1150252577 abstract "This chapter discusses the various aspects of ultrasonic chemical relaxation spectroscopy. Relaxation spectroscopy is considered to have its origins in Maxwell's On the Dynamical Theory of Gases. It is found that in the absence of any relaxation processes, viscosity and the deviation from perfectly adiabatic propagation because of the conduction of heat from compressed to rarefied regions will produce absorption. The magnitude of the deviation from the local equilibrium chemical composition induced by an acoustic wave is calculated, and a justification is presented for the linearization of the equations that describe the reaction kinetics. The heat capacity, compressibility, and coefficient of volume expansion of a concentrated solution may be rather different from those of the solvent, and the contribution of a chemical or structural equilibrium to these properties may, in certain circumstances, be large. It is suggested that for large volume and enthalpy, changes in condensed phases, one may assume that the deviations from equilibrium composition induced by moderate acoustic intensities are small, and that the kinetic equations that describe the time evolution of the composition may be linearized without significant error." @default.
- W1150252577 created "2016-06-24" @default.
- W1150252577 creator A5044761978 @default.
- W1150252577 date "1981-01-01" @default.
- W1150252577 modified "2023-10-18" @default.
- W1150252577 title "4. Ultrasonic Chemical Relaxation Spectroscopy" @default.
- W1150252577 cites W140801292 @default.
- W1150252577 cites W1779784896 @default.
- W1150252577 cites W1969876717 @default.
- W1150252577 cites W1971078265 @default.
- W1150252577 cites W1971559027 @default.
- W1150252577 cites W1973778630 @default.
- W1150252577 cites W1975202002 @default.
- W1150252577 cites W1975400064 @default.
- W1150252577 cites W1975731975 @default.
- W1150252577 cites W1975986134 @default.
- W1150252577 cites W1976652130 @default.
- W1150252577 cites W1976831524 @default.
- W1150252577 cites W1977344336 @default.
- W1150252577 cites W1977508754 @default.
- W1150252577 cites W1978837828 @default.
- W1150252577 cites W1980082111 @default.
- W1150252577 cites W1980434146 @default.
- W1150252577 cites W1980814553 @default.
- W1150252577 cites W1981937247 @default.
- W1150252577 cites W1984143704 @default.
- W1150252577 cites W1985069083 @default.
- W1150252577 cites W1987185779 @default.
- W1150252577 cites W1988319364 @default.
- W1150252577 cites W1990945265 @default.
- W1150252577 cites W1992894403 @default.
- W1150252577 cites W1993299482 @default.
- W1150252577 cites W1993976395 @default.
- W1150252577 cites W1995062017 @default.
- W1150252577 cites W1996224306 @default.
- W1150252577 cites W1999811830 @default.
- W1150252577 cites W2001239791 @default.
- W1150252577 cites W2003200542 @default.
- W1150252577 cites W2003373022 @default.
- W1150252577 cites W2005765652 @default.
- W1150252577 cites W2006148909 @default.
- W1150252577 cites W2007732520 @default.
- W1150252577 cites W2010436681 @default.
- W1150252577 cites W2014666640 @default.
- W1150252577 cites W2017692130 @default.
- W1150252577 cites W2018027789 @default.
- W1150252577 cites W2019089375 @default.
- W1150252577 cites W2019648512 @default.
- W1150252577 cites W2020905223 @default.
- W1150252577 cites W2022973266 @default.
- W1150252577 cites W2024379476 @default.
- W1150252577 cites W2028637277 @default.
- W1150252577 cites W2029141945 @default.
- W1150252577 cites W2031673324 @default.
- W1150252577 cites W2035831026 @default.
- W1150252577 cites W2039813533 @default.
- W1150252577 cites W2042055638 @default.
- W1150252577 cites W2043473124 @default.
- W1150252577 cites W2044949528 @default.
- W1150252577 cites W2047788834 @default.
- W1150252577 cites W2049854801 @default.
- W1150252577 cites W2050203636 @default.
- W1150252577 cites W2053260375 @default.
- W1150252577 cites W2054632829 @default.
- W1150252577 cites W2054660893 @default.
- W1150252577 cites W2055860104 @default.
- W1150252577 cites W2056602613 @default.
- W1150252577 cites W2058400369 @default.
- W1150252577 cites W2062209206 @default.
- W1150252577 cites W2062379111 @default.
- W1150252577 cites W2063070769 @default.
- W1150252577 cites W2063916459 @default.
- W1150252577 cites W2066611317 @default.
- W1150252577 cites W2071696330 @default.
- W1150252577 cites W2072578314 @default.
- W1150252577 cites W2073716361 @default.
- W1150252577 cites W2076588784 @default.
- W1150252577 cites W2076663931 @default.
- W1150252577 cites W2077049068 @default.
- W1150252577 cites W2078281373 @default.
- W1150252577 cites W2078371966 @default.
- W1150252577 cites W2081393298 @default.
- W1150252577 cites W2082954357 @default.
- W1150252577 cites W2087429360 @default.
- W1150252577 cites W2089756494 @default.
- W1150252577 cites W2090579742 @default.
- W1150252577 cites W2093328704 @default.
- W1150252577 cites W2093342359 @default.
- W1150252577 cites W2119812758 @default.
- W1150252577 cites W2128868331 @default.
- W1150252577 cites W2129452833 @default.
- W1150252577 cites W2131819271 @default.
- W1150252577 cites W2141519605 @default.
- W1150252577 cites W2169704717 @default.
- W1150252577 cites W2222369690 @default.
- W1150252577 cites W2313350860 @default.
- W1150252577 cites W2317525333 @default.
- W1150252577 cites W2321133468 @default.